Appears 4 times in the Quran.
22:55 وَلَا يَزَالُ ٱلَّذِينَ كَفَرُوا۟ فِى مِرْيَةٍ مِّنْهُ حَتَّىٰ تَأْتِيَهُمُ ٱلسَّاعَةُ بَغْتَةً أَوْ يَأْتِيَهُمْ عَذَابُ يَوْمٍ عَقِيمٍ
And those who disbelieve shall not cease to be in doubt concerning it until the hour overtakes them suddenly, or there comes on them the chastisement of a destructive day.
42:50 أَوْ يُزَوِّجُهُمْ ذُكْرَانًا وَإِنَٰثًا وَيَجْعَلُ مَن يَشَآءُ عَقِيمًا إِنَّهُۥ عَلِيمٌ قَدِيرٌ
Or He makes them of both sorts, male and female; and He makes whom He pleases barren; surely He is the Knowing, the Powerful.
Then his wife came up in great grief, and she struck her face and said: An old barren woman!
And in Ad: When We sent upon them the destructive wind.